Comparisons for Correlated Methods

Note:  noncorrelated methods were run on a different processor and thus times are not directly comparable.

comp_1.gif (1408 bytes) PM3 6-311G* 6-31G**/B3LYP 6-31G**/LMP2
E (-35.0, liq.) -34.49 -196.3838 -197.7884 -197.0689
C2-C3 (1.537) 1.5202 1.5291 1.535 1.530
H-C-H (109.5) 105.47 106.2 105.9 106.4
Time 2.19 s 69:46.1 6:51 44:35
PM3 6-311G* 6-31G**/B3LYP 6-31G**/LMP2
E (19.82, gas) 23.45 -230.7541 -232.2582 -231.4828
C-C (1.394) 1.3915 1.3853 1.3969 1.393/1.404
H-C-C (120) 120 120 120 120
Time 0.63 s 10:41.7 1:49 34:40
PM3 6-311G* 6-31G**/B3LYP 6-31G**/LMP2
E 30.37 -246.7497 -248.2926 -247.4990
C-N (1.339) 1.3528 1.3197 1.3397 1.342
C2-C3 (1.394) 1.3954 1.3844 1.3962 1.390
Time 1.22 s 85:58.6 6:33 53:35
comp_4.gif (1729 bytes) PM3 6-311G** 6-31G**/B3LYP 6-31G**/LMP2
E -21.50 -421.6076 -422.2252 -422.8646
C=O (1.215) 1.2182 1.1900 1.222 1.233
CPh-C (1.47) 1.4971 1.5048 1.5023 1.511
Dipole 2.685 3.0527
Time 7.08 s 635:13.4 86:05 293:03
comp_5.gif (1877 bytes) PM3 6-31G* 6-31G**/B3LYP 6-31G**/LMP2
E -28.87 -485.2542 -487.2853 -486.0648
CMe-Si (1.870) 1.8931 1.8913 1.894 1.885
Cv-Si (1.843) 1.8422 1.8841 1.882 1.872
C=C (1.335) 1.3215 1.3253 1.339 1.344
Time 14.7 s 304:38.15 55:57 126:09
comp_6.gif (2128 bytes) PM3 6-31G* 6-31G**/B3LYP 6-31G**/LMP2
E -240.58 -759.0949 -762.0609 -760.3507
P=O 1.4486 1.4472 1.482 1.490
P-O (1.65) 1.6832 1.5690 1.606 1.609
C-O (1.426) 1.3904 1.4184 1.440 1.448
O-P-O (99.0) 104.0 105.8 102.0 101.0
Time 1:00 1699:16 204:31 843:33

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12/09/03