CH435/535 Dynamic Behavior Measured by NMR (Part 2) |
We saw previously a broadening of lines in cyclododecatriene. Molecular mechanics reveals a group of low-energy conformers:
CDT_1.pdb |
CDT_2.pdb |
CDT_3.pdb |
CDT_4.pdb |
In this example, the spectroscopic problem may be too challenging if we cool the sample, and
simply raising the temperature becomes the preferred solution to simplifying the spectrum.
Room temperature: